New PDF release: Advances in Controlled/Living Radical Polymerization

By Krzysztof Matyjaszewski

ISBN-10: 0841219591

ISBN-13: 9780841219595

ISBN-10: 0841238545

ISBN-13: 9780841238541

Provides new advancements in controlled/living radical polymerization in 3 parts: atom move radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation move (RAFT). additionally comprises synthesis and characterization of many new materials.

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Extra info for Advances in Controlled/Living Radical Polymerization

Example text

If At from Ref. 32. 17(27). 25 Monomer Conversion, X Figure 5. Exponent a obtained byfittingeq 8 to SP-PLP traces for MA (open circles), BA (triangles), DMA (full circles) at 1000 bar, MMA (squares) at 2000 bar, all at 40°C. The straight line refers to the mean value a = 0Λ5. 15, represented by the straight line in the picture. 16 predicted by Friedman and O'Shaughnessy (28, 29) for chemically controlled and for diffusion controlled termination reactions in dilute polymer solution o f sufficiently large free radicals with radical functionality at (or close to) terminal positions of the macromolecular chain.

The significant scatter on the M M A lkp data is due to high k and low kp which is associated with unfavorable S P - P L P signal-to-noise quality. lkp is more or less constant at low X. As the propagation rate coefficient for both M M A and D A homopolymerization will not vary with conversion, the change of /kp with X in both homopolymerizations is entirely due to changes of . ; ACS Symposium Series; American Chemical Society: Washington, DC, 2003. 8 Monomer Conversion, X Figure 1.

W. C. 20036 ACS Symposium Series; American Chemical Society: Washington, DC, 2003. 48 The data points exhibit some cluster-type structure which is due to the slight variation OÎ/ÔMA with X that allows for deducing &,copo at (slightly) different/DMA from successive S P - P L P experiments carried out during one copolymerization experiment at increasing X. The log vs. / D M A correlation is curved for D M A - Μ Α and thus differs from the corresponding close-to-linear relation observed with the intra-family D A - M A system (dotted line in Figure 2) (6, 7).

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Advances in Controlled/Living Radical Polymerization by Krzysztof Matyjaszewski

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