By F G A Stone; Robert West
ADVANCES ORGANOMETALLIC CHEMISTRY V 7.
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Extra info for Advances in Organometallic Chemistry, 7
The strenuously advocated case by A. Kekuld and others for a fixity in valence found support, therefore, in the early work with organometallic compounds. It is interesting to note how the whole picture of valence, as it concerned organometallic compounds, changed over the years; at first, organometallic chemistry did much to sustain the fixity of valence ;later, it provided a very useful tool to establish the wide variability in valence for certain elements. M. Gomberg, and others, in their early and epochal work establishing the existence of trivalent carbon in triarylmethyls, put to great use the synthetic possibilities of organometallic compounds for the preparation of the necessary hexaarylethanes.
52, No. 1, 77 (1953). 23. , and Eisch, J. , Sci. Am. 208, No. 1 , 89 (1963). 24. , and Heckert, L. , J . Am. Chem. 42,1010 (1920). 25. , Jones, R. , Martin. G. , Nobis, J. , Thirtle, J. , Yale, H. , and Yeoman, F. , J. Am. Chem. SOC. 78, 2790 (1956); and subsequent papers in this series. 26. , in “Encyclopaedia Britannica,” Vol. 16, p. 1089. Benton, London, 1966. 27. , and Schwebke, G. , Adwan. Organometal. Chem. 1,89 (1964). 28. , and Winkler, H. J. , in “Organometallic Chemistry” (H. ), p. 270.
Advances in Organometallic Chemistry, 7 by F G A Stone; Robert West